➦   Charged and metallic molecular monolayers through surface-induced aromatic stabilization

➦   An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen

➦   Highly ordered alignment of a vinyl polymer by host–guest cross-polymerization

➦   A multistep single-crystal-to-single-crystal bromodiacetylene dimerization

➦   Enzyme-free translation of DNA into sequence-defined synthetic polymers structurally unrelated to nu

➦   Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption

➦   Product-state-resolved dynamics of the elementary reaction of atomic oxygen with molecular hydrogen,

➦   Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters

➦   A homogeneous transition metal complex for clean hydrogen production from methanol–water mixtures

➦   Synthesis of 19-substituted geldanamycins with altered conformations and their binding to heat shock

➦   Enantioselective synthesis of tatanans A–C and reinvestigation of their glucokinase-activating prope

➦   Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic

➦   The essential role of charge-shift bonding in hypervalent prototype XeF2

➦   Label-assisted mass spectrometry for the acceleration of reaction discovery and optimization

➦   Catalytic control over supramolecular gel formation

➦   Chemistry inside molecular containers in the gas phase

➦   Decoupling hydrogen and oxygen evolution during electrolytic water splitting using an electron-coupl

➦   The hydrodeoxygenation of bioderived furans into alkanes

➦   Single-nanoparticle phase transitions visualized by four-dimensional electron microscopy

➦   Prebiotically plausible oligoribonucleotide ligation facilitated by chemoselective acetylation

➦   The use of elemental sulfur as an alternative feedstock for polymeric materials

➦   Functional RNAs exhibit tolerance for non-heritable 2′–5′ versus 3′–5′ backbone heterogeneity

➦   Probing the biophysical interplay between a viral genome and its capsid

➦   Switching radical stability by pH-induced orbital conversion

➦   Isolation and characterization of a uranium(VI)–nitride triple bond

➦   Electrostatically gated membrane permeability in inorganic protocells

➦   Competition of shape and interaction patchiness for self-assembling nanoplates

➦   Magnetic blocking in a linear iron(I) complex

➦   Charging a Li–O2 battery using a redox mediator

➦   Heterogenized cobalt oxide catalysts for nitroarene reduction by pyrolysis of molecularly defined co

➦   Competition between model protocells driven by an encapsulated catalyst

➦   Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and

➦   RNA with iron(II) as a cofactor catalyses electron transfer

➦   Simultaneous structure–activity studies and arming of natural products by C–H amination reveal cellu

➦   Initiation of carbon nanotube growth by well-defined carbon nanorings

➦   Studying the role of protein dynamics in an SN2 enzyme reaction using free-energy surfaces and solve

➦   A family of zeolites with controlled pore size prepared using a top-down method

➦   Detection of different oxidation states of individual manganese porphyrins during their reaction wit

➦   Biomolecular robotics for chemomechanically driven guest delivery fuelled by intracellular ATP

➦   Direct probe of spectral inhomogeneity reveals synthetic tunability of single-nanocrystal spectral l

➦   Sustained gastrointestinal activity of dendronized polymer–enzyme conjugates

➦   Entangled quantum electronic wavefunctions of the Mn4CaO5 cluster in photosystem II

➦   A robustness screen for the rapid assessment of chemical reactions

➦   Direct catalytic cross-coupling of organolithium compounds

➦   The Janus-faced role of external forces in mechanochemical disulfide bond cleavage

➦   A pentagonal cyanostar macrocycle with cyanostilbene CH donors binds anions and forms dialkylphospha

➦   Stabilization of anti-aromatic and strained five-membered rings with a transition metal

➦   On the nature and origin of dicationic, charge-separated species formed in liquid water on X-ray irr

➦   Single-molecule interrogation of a bacterial sugar transporter allows the discovery of an extracellu

➦   A dendritic single-molecule fluorescent probe that is monovalent, photostable and minimally blinking