➦ Non-oxidative intercalation and exfoliation of graphite by Brønsted acids
➦ Tailored hierarchical micelle architectures using living crystallization-driven self-assembly in two
➦ Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(II
➦ Dynamic covalent chemistry of bisimines at the solid/liquid interface monitored by scanning tunnelli
➦ 5-Hydroxymethylcytosine is a predominantly stable DNA modification
➦ Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilyla
➦ Recognition and sensing of low-epitope targets via ternary complexes with oligonucleotides and synth
➦ Atom-efficient regioselective 1,2-dearomatization of functionalized pyridines by an earth-abundant o
➦ Self-assembling hydrogel scaffolds for photocatalytic hydrogen production
➦ Switching on the fluorescence of 2-aminopurine by site-selective microhydration
➦ DNA brick crystals with prescribed depths
➦ Discovering chemistry with an ab initio nanoreactor
➦ Molecular motor-driven abrupt anisotropic shape change in a single crystal of a Ni complex
➦ Mechanistic, crystallographic, and computational studies on the catalytic, enantioselective sulfenof
➦ Revealing the macromolecular targets of complex natural products
➦ The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li–O2 batte
➦ Structure of a designed protein cage that self-assembles into a highly porous cube
➦ Rhodanine hydrolysis leads to potent thioenolate mediated metallo-β-lactamase inhibition
➦ Covalent functionalization of monolayered transition metal dichalcogenides by phase engineering
➦ Pseudopterosin synthesis from a chiral cross-conjugated hydrocarbon through a series of cycloadditio
➦ Halogen bonding in water results in enhanced anion recognition in acyclic and rotaxane hosts
➦ Supramolecular binding and separation of hydrocarbons within a functionalized porous metal–organic f
➦ Substrate control in stereoselective lanthionine biosynthesis
➦ Spatially resolved analysis of short-range structure perturbations in a plastically bent molecular c
➦ Screening and classifying small-molecule inhibitors of amyloid formation using ion mobility spectrom
➦ Quantitative mapping of zinc fluxes in the mammalian egg reveals the origin of fertilization-induced
➦ Exploring the sequence space for (tri-)peptide self-assembly to design and discover new hydrogels
➦ Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueou
➦ Copper-catalysed selective hydroamination reactions of alkynes
➦ Catalytic, stereospecific syn-dichlorination of alkenes
➦ On the origin of the stability of graphene oxide membranes in water
➦ Rational design of functional and tunable oscillating enzymatic networks
➦ Catalytic enantioselective synthesis of indanes by a cation-directed 5-endo-trig cyclization
➦ Concerted proton-coupled electron transfer from a metal-hydride complex
➦ Trapping virtual pores by crystal retro-engineering
➦ Dual-display of small molecules enables the discovery of ligand pairs and facilitates affinity matur
➦ Synthesis and characterization of hexaarylbenzenes with five or six different substituents enabled b
➦ Coulomb explosion during the early stages of the reaction of alkali metals with water
➦ Heat flux across an open pore enables the continuous replication and selection of oligonucleotides t
➦ Atropselective syntheses of (−) and (+) rugulotrosin A utilizing point-to-axial chirality transfer
➦ A subset of annular lipids is linked to the flippase activity of an ABC transporter
➦ Supramolecular nesting of cyclic polymers
➦ Molecular length dictates the nature of charge carriers in single-molecule junctions of oxidized oli
➦ Terpene cyclization catalysed inside a self-assembled cavity
➦ Stereoelectronic switching in single-molecule junctions
➦ Stepwise growth of surface-grafted DNA nanotubes visualized at the single-molecule level
➦ Intermediate tunnelling–hopping regime in DNA charge transport
➦ Combined biomass valorization and hydrogen production in a photoelectrochemical cell
➦ Inducing and quantifying forbidden reactivity with single-molecule polymer mechanochemistry