➦   On the mechanism of vibrational control of light-induced charge transfer in donor–bridge–acceptor as

➦   A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate

➦   Diverse sp3 C−H functionalization through alcohol β-sulfonyloxylation

➦   A cascade reaction network mimicking the basic functional steps of adaptive immune response

➦   How do metal ions direct ribozyme folding?

➦   Formal SiH4 chemistry using stable and easy-to-handle surrogates

➦   An eight-step synthesis of epicolactone reveals its biosynthetic origin

➦   Switchable selectivity in an NHC-catalysed dearomatizing annulation reaction

➦   Structure of a PEGylated protein reveals a highly porous double-helical assembly

➦   Iterative exponential growth of stereo- and sequence-controlled polymers

➦   Latent analysis of unmodified biomolecules and their complexes in solution with attomole detection s

➦   Cooperative singlet and triplet exciton transport in tetracene crystals visualized by ultrafast micr

➦   Efficient green methanol synthesis from glycerol

➦   Spatially resolved multicomponent gels

➦   Shaping quaternary assemblies of water-soluble non-peptide helical foldamers by sequence manipulatio

➦   Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts

➦   Molecular hydrogen interacts more strongly when rotationally excited at low temperatures leading to

➦   Co-assembly, spatiotemporal control and morphogenesis of a hybrid protein–peptide system

➦   Iron sensitizer converts light to electrons with 92% yield

➦   A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp3)–H amination

➦   Unidirectional rotary motion in achiral molecular motors

➦   O-GlcNAc modification blocks the aggregation and toxicity of the protein α-synuclein associated with

➦   Cage connectivity and frontier π orbitals govern the relative stability of charged fullerene isomers

➦   Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids

➦   Diastereoselective addition of Grignard reagents to α-epoxy N-sulfonyl hydrazones

➦   A labile hydride strategy for the synthesis of heavily nitridized BaTiO3

➦   Real-time observation of multiexcitonic states in ultrafast singlet fission using coherent 2D electr

➦   Monitoring one-electron photo-oxidation of guanine in DNA crystals using ultrafast infrared spectros

➦   A steric tethering approach enables palladium-catalysed C–H activation of primary amino alcohols

➦   Synthesis of ‘unfeasible’ zeolites

➦   Efficient, non-toxic anion transport by synthetic carriers in cells and epithelia

➦   Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via TiII/TiIV redox catalys

➦   Nickel-catalysed Suzuki–Miyaura coupling of amides

➦   Reconstitution of [Fe]-hydrogenase using model complexes

➦   Inhibition of human copper trafficking by a small molecule significantly attenuates cancer cell prol

➦   Synthesis of giant globular multivalent glycofullerenes as potent inhibitors in a model of Ebola vir

➦   Local vibrational coherences drive the primary photochemistry of vision

➦   Quantitative self-assembly of a purely organic three-dimensional catenane in water

➦   A supramolecular helix that disregards chirality

➦   Highly branched and loop-rich gels via formation of metal–organic cages linked by polymers

➦   Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization

➦   Controlling and imaging biomimetic self-assembly

➦   A threading receptor for polysaccharides

➦   Catching elusive glycosyl cations in a condensed phase with HF/SbF5 superacid

➦   Influence of the leaving group on the dynamics of a gas-phase SN2 reaction

➦   Incorporation of well-dispersed sub-5-nm graphitic pencil nanodots into ordered mesoporous framework

➦   Phosphorylation-mediated RNA/peptide complex coacervation as a model for intracellular liquid organe

➦   Self-assembling biomolecular catalysts for hydrogen production

➦   Conversion of alkanes to linear alkylsilanes using an iridium–iron-catalysed tandem dehydrogenation–

➦   Pick-up, transport and release of a molecular cargo using a small-molecule robotic arm