➦ Accelerated chemistry in the reaction between the hydroxyl radical and methanol at interstellar temp
➦ Total synthesis of the Daphniphyllum alkaloid daphenylline
➦ Ultrafast above-threshold dynamics of the radical anion of a prototypical quinone electron-acceptor
➦ A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes
➦ Magnetic relaxation pathways in lanthanide single-molecule magnets
➦ A grossly warped nanographene and the consequences of multiple odd-membered-ring defects
➦ Brightening of carbon nanotube photoluminescence through the incorporation of sp3 defects
➦ β-Carbon activation of saturated carboxylic esters through N-heterocyclic carbene organocatalysis
➦ Conditionally fluorescent molecular probes for detecting single base changes in double-stranded DNA
➦ On the cooperative formation of non-hydrogen-bonded water at molecular hydrophobic interfaces
➦ Exceptional oxidation activity with size-controlled supported gold clusters of low atomicity
➦ Enantioselective silyl protection of alcohols promoted by a combination of chiral and achiral Lewis
➦ Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylat
➦ Mechanochemical strengthening of a synthetic polymer in response to typically destructive shear forc
➦ Sub-ångström-resolution crystallography reveals physical distortions that enhance reactivity of a co
➦ Catalyst recognition of cis-1,2-diols enables site-selective functionalization of complex molecules
➦ Constructing monocrystalline covalent organic networks by polymerization
➦ A strategy for the diversity-oriented synthesis of macrocyclic scaffolds using multidimensional coup
➦ Water lubricates hydrogen-bonded molecular machines
➦ Site-specific positioning of dendritic alkyl chains on DNA cages enables their geometry-dependent se
➦ A broadly applicable [18F]trifluoromethylation of aryl and heteroaryl iodides for PET imaging
➦ Component-based syntheses of trioxacarcin A, DC-45-A1 and structural analogues
➦ A missing link in the transformation from asymmetric to symmetric metallofullerene cages implies a t
➦ End-to-end conformational communication through a synthetic purinergic receptor by ligand-induced he
➦ Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene
➦ Optical control of antibacterial activity
➦ A clamp-like biohybrid catalyst for DNA oxidation
➦ Computer-aided molecular design of solvents for accelerated reaction kinetics
➦ Caesium in high oxidation states and as a p-block element
➦ Water vibrations have strongly mixed intra- and intermolecular character
➦ Fluctuating exciton localization in giant π-conjugated spoked-wheel macrocycles
➦ Pattern transformation with DNA circuits
➦ In situ growth of nanoparticles through control of non-stoichiometry
➦ Layer-by-layer cell membrane assembly
➦ Metal-free binding and coupling of carbon monoxide at a boron–boron triple bond
➦ A thiamin-utilizing ribozyme decarboxylates a pyruvate-like substrate
➦ Large negative thermal expansion of a polymer driven by a submolecular conformational change
➦ A boron–boron coupling reaction between two ethyl cation analogues
➦ How much do van der Waals dispersion forces contribute to molecular recognition in solution?
➦ In-ice evolution of RNA polymerase ribozyme activity
➦ Bacteria clustering by polymers induces the expression of quorum-sensing-controlled phenotypes
➦ Rapid assembly of complex cyclopentanes employing chiral, α,β-unsaturated acylammonium intermediates
➦ Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of t
➦ Singlet exciton fission in solution
➦ Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy
➦ Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of
➦ Biogenetically inspired synthesis and skeletal diversification of indole alkaloids
➦ Visualization and selective chemical targeting of RNA G-quadruplex structures in the cytoplasm of hu
➦ Oligomerization transforms human APOBEC3G from an efficient enzyme to a slowly dissociating nucleic