➦   High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium

➦   Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture

➦   A ‘Texas-sized’ molecular box that forms an anion-induced supramolecular necklace

➦   Million-fold activation of the [Fe2(µ-O)2] diamond core for C–H bond cleavage

➦   Quantum size effects in ambient CO oxidation catalysed by ligand-protected gold clusters

➦   Self-assembly and optically triggered disassembly of hierarchical dendron–virus complexes

➦   Charge-transfer-induced structural rearrangements at both sides of organic/metal interfaces

➦   Preparation of functionalized organoaluminiums by direct insertion of aluminium to unsaturated halid

➦   Catalyst selection based on intermediate stability measured by mass spectrometry

➦   The rational design of helium bonds

➦   Assembly of a metal–organic framework by sextuple intercatenation of discrete adamantane-like cages

➦   An organic redox electrolyte to rival triiodide/iodide in dye-sensitized solar cells

➦   Rapid preparation of flexible porous coordination polymer nanocrystals with accelerated guest adsorp

➦   Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

➦   Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts

➦   Geometry-controlled kinetics

➦   Enhancement of anhydrous proton transport by supramolecular nanochannels in comb polymers

➦   Using first principles to predict bimetallic catalysts for the ammonia decomposition reaction

➦   Direct detection of CH/π interactions in proteins

➦   Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

➦   Enantioselective iron-catalysed O–H bond insertions

➦   Ion-triggered spring-like motion of a double helicate accompanied by anisotropic twisting

➦   Electrochemistry through glass

➦   Mechanistic insights into the ruthenium-catalysed diene ring-closing metathesis reaction

➦   Nucleophilic catalysis of acylhydrazone equilibration for protein-directed dynamic covalent chemistr

➦   Direct transformation of graphene to fullerene

➦   Experimental evidence for the functional relevance of anion–π interactions

➦   Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bi

➦   Synthesis of a metal oxide with a room-temperature photoreversible phase transition

➦   Chiral-auxiliary-mediated 1,2-cis-glycosylations for the solid-supported synthesis of a biologically

➦   Convergent and stereospecific synthesis of complex skipped polyenes and polyunsaturated fatty acids

➦   Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

➦   From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stabl

➦   Photoreactivity examined through incorporation in metal−organic frameworks

➦   Structural evolution during the reduction of chemically derived graphene oxide

➦   Monodisperse cylindrical micelles by crystallization-driven living self-assembly

➦   Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination p

➦   Hydroacylation of α,β-unsaturated esters via aerobic C–H activation

➦   Cascading transformations within a dynamic self-assembled system

➦   Reversible dioxygen binding in solvent-free liquid myoglobin

➦   Lewis acid-catalysed formation of two-dimensional phthalocyanine covalent organic frameworks

➦   Singlet fission in pentacene through multi-exciton quantum states

➦   Sequence-selective assembly of tweezer molecules on linear templates enables frameshift-reading of s

➦   A layered ionic crystal of polar Li@C60 superatoms

➦   Etching and narrowing of graphene from the edges

➦   Molecules containing rare-earth atoms solely bonded by transition metals

➦   Computational evidence that hyperconjugative interactions are not responsible for the anomeric effec

➦   Isolation of a radical dianion of nitrogen oxide (NO)2−

➦   Electrically induced bonding of DNA to gold

➦   Two- and three-dimensional extended solids and metallization of compressed XeF2