➦ Enantioselective photoinduced cyclodimerization of a prochiral anthracene derivative adsorbed on hel
➦ A silicon–carbonyl complex stable at room temperature
➦ Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines
➦ Enhanced reactivity of twisted amides inside a molecular cage
➦ Aerobic radical polymerization mediated by microbial metabolism
➦ State-to-state scattering of highly vibrationally excited NO at broadly tunable energies
➦ FAD-dependent enzyme-catalysed intermolecular [4+2] cycloaddition in natural product biosynthesis
➦ Spontaneous drying of non-polar deep-cavity cavitand pockets in aqueous solution
➦ Engineered triply orthogonal pyrrolysyl–tRNA synthetase/tRNA pairs enable the genetic encoding of th
➦ In situ chromatin interactomics using a chemical bait and trap approach
➦ Ruthenium-catalysed multicomponent synthesis of the 1,3-dienyl-6-oxy polyketide motif
➦ Cobalt-catalysed C–H methylation for late-stage drug diversification
➦ A site-selective amination catalyst discriminates between nearly identical C–H bonds of unsymmetrica
➦ α-Synuclein aggregation nucleates through liquid–liquid phase separation
➦ Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions
➦ Iridium single-atom catalyst on nitrogen-doped carbon for formic acid oxidation synthesized using a
➦ Synthesis and characterization of crystalline niobium and tantalum carbonyl complexes at room temper
➦ Enantioselective radical C–H amination for the synthesis of β-amino alcohols
➦ Emergence of light-driven protometabolism on recruitment of a photocatalytic cofactor by a self-repl
➦ Modulation of porosity in a solid material enabled by bulk photoisomerization of an overcrowded alke
➦ NH3 formation from N2 and H2 mediated by molecular tri-iron complexes
➦ Synthesis of a d1-titanium fluoride kagome lattice antiferromagnet
➦ Time-dependent enantiodivergent synthesis via sequential kinetic resolution
➦ Dual electrocatalysis enables enantioselective hydrocyanation of conjugated alkenes
➦ Structural snapshots of the minimal PKS system responsible for octaketide biosynthesis
➦ Tunable exciton binding energy in 2D hybrid layered perovskites through donor–acceptor interactions
➦ Fast motion of molecular rotors in metal–organic framework struts at very low temperatures
➦ Identification of targets of AMPylating Fic enzymes by co-substrate-mediated covalent capture
➦ Discovery and evolution of RNA and XNA reverse transcriptase function and fidelity
➦ Barcoded DNA origami structures for multiplexed optimization and enrichment of DNA-based protein-bin
➦ Tracking the ultraviolet-induced photochemistry of thiophenone during and after ultrafast ring openi
➦ Single-molecule visualization of DNA G-quadruplex formation in live cells
➦ Stereoselective access to [5.5.0] and [4.4.1] bicyclic compounds through Pd-catalysed divergent high
➦ Three concomitant C–C dissociation pathways during the mechanical activation of an N-heterocyclic ca
➦ CD44 regulates epigenetic plasticity by mediating iron endocytosis
➦ Acyltransferase that catalyses the condensation of polyketide and peptide moieties of goadvionin hyb
➦ Knotting a molecular strand can invert macroscopic effects of chirality
➦ Complexes featuring a linear [N≡U≡N] core isoelectronic to the uranyl cation
➦ A monodomain class II terpene cyclase assembles complex isoprenoid scaffolds
➦ De novo engineering of intracellular condensates using artificial disordered proteins
➦ A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transf
➦ Audible sound-controlled spatiotemporal patterns in out-of-equilibrium systems
➦ Ribosomal synthesis and de novo discovery of bioactive foldamer peptides containing cyclic β-amino a
➦ Post-translational formation of strained cyclophanes in bacteria
➦ Design of a small molecule that stimulates vascular endothelial growth factor A enabled by screening
➦ A platinum(ii) metallonitrene with a triplet ground state
➦ Using sulfuramidimidoyl fluorides that undergo sulfur(vi) fluoride exchange for inverse drug discove
➦ Atomic mechanism of metal crystal nucleus formation in a single-walled carbon nanotube
➦ Quantum machine learning using atom-in-molecule-based fragments selected on the fly